INTRAMOLECULAR REACTIONS OF ALLYLOXY RADICALS FEATURING 6-CENTERED TRANSITION-STATES - REGIOCHEMISTRY AND STEREOCHEMISTRY

被引：10

作者：

BEGLEY, MJ ^{[1
]}

HOUSDEN, N ^{[1
]}

JOHNS, A ^{[1
]}

MURPHY, JA ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

TETRAHEDRON | 1991年 / 47卷 / 39期

关键词：

ALLYLOXY RADICALS; CYCLOPENTANOLS; TETRAHYDROPYRANS; STEREOSELECTIVE; EPOXIDES;

D O I：

10.1016/S0040-4020(01)96183-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intramolecular free-radical reactions of allyloxy radicals to form tetrahydropyrans and cyclopentanols have been studied; the cyclopentanols form stereoselectively with trans disposition of groups about the ring-forming bond.

引用

页码：8417 / 8430

页数：14

共 25 条

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