RATIONAL DESIGN OF MN-SALEN EPOXIDATION CATALYSTS - PRELIMINARY-RESULTS

被引：99

作者：

HOSOYA, N ^{[1
]}

HATAYAMA, A ^{[1
]}

IRIE, R ^{[1
]}

SASAKI, H ^{[1
]}

KATSUKI, T ^{[1
]}

机构：

[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON | 1994年 / 50卷 / 15期

关键词：

D O I：

10.1016/S0040-4020(01)89368-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(Salen)manganese(III) complex 7 designed on the basis of the new proposal on the olefin's access to metal-oxo bond and complex 10 having axial chirality in salicylaldehyde part were found to be effective catalysts for the epoxidation of unfunctionalized olefins, especially for cis-olefins.

引用

页码：4311 / 4322

页数：12

共 22 条

[21] ENANTIOSELECTIVE EPOXIDATION OF UNFUNCTIONALIZED OLEFINS WITH MOLECULAR-OXYGEN AND ALDEHYDE CATALYZED BY OPTICALLY-ACTIVE MANGANESE(III) COMPLEXES [J].

YAMADA, T ;

IMAGAWA, K ;

NAGATA, T ;

MUKAIYAMA, T .

CHEMISTRY LETTERS, 1992, (11) :2231-2234

[22] ENANTIOSELECTIVE EPOXIDATION OF UNFUNCTIONALIZED OLEFINS CATALYZED BY (SALEN)MANGANESE COMPLEXES [J].

ZHANG, W ;

LOEBACH, JL ;

WILSON, SR ;

JACOBSEN, EN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (07) :2801-2803

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