SILAKETALS AS TETHERS IN INTRAMOLECULAR RADICAL CYCLIZATIONS

被引：44

作者：

HUTCHINSON, JH

DAYNARD, TS

GILLARD, JW

机构：

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 05期

关键词：

D O I：

10.1016/S0040-4039(00)74830-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Intramolecular radical cyclisation reactions of substrates possessing a silaketal tether proceed predominantly via an endo mode in moderate to good yield to give 7, 8 or 9 membered ring products. The products, which are protected diols, can then be deprotected using standard conditions.

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页码：573 / 576

页数：4

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