ON THE DYNAMIC AND STATIC NATURE OF ROTARY CRYSTALS - EXAMPLES FROM NORMAL PARAFFINS

被引：9

作者：

FILATOV, SK

KOTELNIKOVA, EN

RASTORGUYEVA, IE

机构：

[1] Department of Crystallography, Faculty of Geology, Leningrad State University, Leningrad 199034

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1991年 / 194卷 / 3-4期

关键词：

ROTARY CRYSTALS; NORMAL PARAFFINS; TEMPERATURE;

D O I：

10.1524/zkri.1991.194.3-4.253

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The evidencies for the dynamic but not the static nature of "rotary" crystals are given for normal paraffins as an example. Distinctive features of thermal deformations and polymorphic transformations of paraffins as well as breakdown of paraffin solid solutions at rising temperatures (in a limited temperature interval) indicate the leading role played by the rotary thermal motion of aliphatic chains about their axes in these processes.

引用

页码：253 / 260

页数：8

共 4 条

[1] LIMITS OF ISOMORPHOUS SUBSTITUTION OF CNH2N+2 CHAINS IN PARAFFINS AS A FUNCTION OF TEMPERATURE
FILATOV, SK
KOTELNIKOVA, EN
GOLYNSKAYA, OA
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1989, 188 (3-4): : 161 - 167
[2] HIGH-TEMPERATURE CRYSTAL-CHEMISTRY OF NORMAL ODD PARAFFINS
FILATOV, SK
KOTELNIKOVA, EN
ALEKSANDROVA, EA
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1985, 172 (1-2): : 35 - 43
[3] FILTOV SK, 1987, GEOCHEMICAL IDEAS VE, P141
[4] Kitaygorodsky A. I., 1971, MOL CRYSTALS, P424

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