COMPLEX MISCIBILITY BEHAVIOR FOR POLYMER BLENDS IN FLOW

被引：49

作者：

FERNANDEZ, ML

HIGGINS, JS

HORST, R

WOLF, BA

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM ENGN,LONDON SW7 2BY,ENGLAND

[2] UNIV MAINZ,INST PHYS CHEM,D-55099 MAINZ,GERMANY

来源：

POLYMER | 1995年 / 36卷 / 01期

关键词：

SHEAR; POLYMER BLENDS; MISCIBILITY;

D O I：

10.1016/0032-3861(95)90686-V

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Experimental observations of the effect of shear flow on the miscibility of binary polymer blends an compared to calculations based on a generalized Gibbs energy of mixing G gamma. This mixing free energy characterizes the steady state established at shear rate gamma, as the sum of G(Z), the equilibrium Gibbs energy and E(S), the energy the system stores while flowing.

引用

页码：149 / 154

页数：6

共 34 条

[1] COMPARISON BETWEEN MORPHOLOGY AND RELAXATION PROCESSES IN PARTIALLY PHASE-SEPARATED POLYMER BLENDS [J].