A NEW LAYERED TERNARY SULFIDE - FORMATION OF CU2WS4 BY REACTION OF WS42- AND CU+ IONS

被引：62

作者：

PRUSS, EA

SNYDER, BS

STACY, AM

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

[2] ROHM & HAAS CO,SPRING HOUSE,PA 19477

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1002/anie.199302561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intact tetrathiotungstate units, which are linked into layers by copper(I) ions, are found in the title compound. This can be prepared from [Cu(CH3CN)4]BF4 and (NH4)2WS4 under very mild reaction conditions (135-degrees-C, in solution). The structure of this ternary sulfide was determined by X-ray powder diffraction. + = Cu, Circle = S, . = W.

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页码：256 / 257

页数：2

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