(TRIPHENYLPHOSPHINE) PLATINUM PHENYLACETYLIDES

被引：60

作者：

COLLAMATI, I

FURLANI, A

机构：

[1] Istituto di Chimica Generale ed Inorganica dell' Unìversità di Roma, Centro di Chimica dei Composti di Coordinazione, C.N.R., Rome

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 17卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)88232-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some new Pt acetylides have been made from cis- and trans-(PPh3)2PtCl2 and NaCCPh in liquid ammonia. Both cis- and trans-(PPh3)2Pt(CCPh)2 are obtained if the reaction is carried out in the presence of an excess of NaCCPh. The cis complex is the first example of a cis platinum acetylide. The complex (PPh3)2 PtCl(CCPh), probably in the trans form, is obtained when the reaction is carried out in a 1 : 1 molar ratio. Chemical and physical properties of compounds are described. © 1969.

引用

页码：457 / +

页数：1

共 13 条

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