PREPARATION PROPERTIES AND REACTIONS OF POLYCHLOROAMINE DERIVATIVES

被引：18

作者：

HOLTSCHMIDT, H

DEGENER, E

SCHMELZE.HG

TARNOW, H

ZECHER, W

机构：

[1] Farbenfabriken Bayer AG, Leverkusen, 509, Bayerwerk

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1968年 / 7卷 / 11期

关键词：

Amines; Chlorination; Chloroamines; Polychloroamines; Synthetic methods;

D O I：

10.1002/anie.196808561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly chlorinated amine derivatives can be prepared by the high‐temperature chlorination of amines and amine derivatives. Essential for the success of this reaction is an adequate temperature control suited to the constitution of the amines. In many cases the chlorination products achieve stability by cleavage reactions with formation of the imidic acid chloride or isocyanide dichloride grouping. Cyclic compounds are formed under special conditions. The chlorination process described can be used to obtain e.g. polychloroaryl and polychloroalkyl isocyanide dichlorides, polychloroaryl and polychloroalkyl imidic acid chlorides, and polychloroheterocyclic compounds. Copyright © 1968 by Verlag Chemie, GmbH, Germany

引用

页码：856 / +

页数：1

共 71 条

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