MICROWAVE AND RADIO-FREQUENCY SPECTRUM OF XEHCL

被引：47

作者：

CHANCE, KV ^{[1
]}

BOWEN, KH ^{[1
]}

WINN, JS ^{[1
]}

KLEMPERER, W ^{[1
]}

机构：

[1] HARVARD UNIV,DEPT CHEM,CAMBRIDGE,MA 02138

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 11期

关键词：

D O I：

10.1063/1.437356

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Microwave and radio frequency spectra of 132XeH35Cl are measured by molecular beam electric resonance spectroscopy. The spectroscopic constants determined for this complex are B=989.262 (5) Mhz, DJ=3.84 (32) kHz, (eqQ)a 35Cl=-34.640 (20) MHz, μa=1.0901 (30) D. Only a single vibrational level, with zero angular momentum along the heavy atom axis, has been observed. The results are interpreted in terms of a linear complex with large amplitude oscillation. The structure is assumed to have atomic arrangement XeHCl. The average Xe-Cl distance is 4.258 Å. The average angle of the HCl subunit with the heavy atom axis is 34.8°. The stretching frequency of the weak bond is 33.5 cm-1. © 1979 American Institute of Physics.

引用

页码：5157 / 5160

页数：4

共 19 条

[1] BOWEN KH, 1977, THESIS HARVARD U
[2] THERMODYNAMICS OF LIQUID-MIXTURES OF XENON AND HYDROGEN-CHLORIDE
CALADO, JCG
KOZDON, AF
MORRIS, PJ
DAPONTE, MN
STAVELEY, LAK
WOOLF, LA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1975, 71 (06): : 1372 - 1378
[3] THERMODYNAMICS OF BINARY-LIQUID MIXTURES INVOLVING HYDROGEN BROMIDE, HYDROGEN-CHLORIDE AND XENON
CALADO, JCG
GRAY, CG
GUBBINS, KE
PALAVRA, AMF
SOARES, VAM
STAVELEY, LAK
TWU, CH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 : 893 - 911
[4] CHANCE KV, 1977, THESIS HARVARD U
[5] BOUND ATOM-DIATOMIC MOLECULE COMPLEXES - ANISOTROPIC INTER-MOLECULAR POTENTIALS FOR HYDROGEN RARE GAS SYSTEMS
DUNKER, AM
GORDON, RG
[J]. JOURNAL OF CHEMICAL PHYSICS, 1978, 68 (02) : 700 - 725
[6] Gordon Reich, COMMUNICATION
[7] WIDTHS AND SHIFTS OF H-35CL LINES IN FUNDAMENTAL BAND INDUCED BY ARGON AND XENON AT LOW-TEMPERATURES
HOUDEAU, JP
LARVOR, M
HAEUSLER, C
[J]. JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 1976, 16 (05) : 457 - 465
[8] HOWARD BJ, COMMUNICATION
[9] ANISOTROPIC INTERMOLECULAR POTENTIALS FROM AN ANALYSIS OF SPECTRA OF H2-INERT AND D2-INERT GAS COMPLEXES
LEROY, RJ
VANKRANE.J
[J]. JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (11) : 4750 - 4769
[10] NOBLE-GAS BROADENING OF VIBRATION-ROTATION LINES BELONGING TO DIATOMIC-MOLECULES .1. EXPERIMENTAL RESULTS FOR HCL LINESHIFTS AND WIDTHS
LEVY, A
PIOLLETM.E
BOULET, C
[J]. JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 1973, 13 (07) : 673 - 682

← 1 2 →