ASYMMETRIC CYCLIZATION REACTIONS - CYCLIZATION OF SUBSTITUTED 4-PENTENALS INTO CYCLOPENTANONE DERIVATIVES BY RHODIUM(I) WITH CHIRAL LIGANDS

被引：71

作者：

TAURA, Y ^{[1
]}

TANAKA, M ^{[1
]}

WU, XM ^{[1
]}

FUNAKOSHI, K ^{[1
]}

SAKAI, K ^{[1
]}

机构：

[1] KYUSHU UNIV,FAC PHARMACEUT SCI,MAIDASHI 3-1-1,HIGASHI KU,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON | 1991年 / 47卷 / 27期

关键词：

ASYMMETRIC CYCLIZATION; WILKINSON COMPLEX; RHODIUM; CHIRAL LIGAND; CYCLOPENTANONE;

D O I：

10.1016/S0040-4020(01)80954-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric cyclization of substituted 4-pentenals (Ia,b,c; IIa,b,c,d) by Rh(I) with chiral ligands was tested, and substrate (IId) with a bulkier substituent at C4 underwent more stereoselective cyclization by Rh(I)-((+)-DIPMC) to yield substituted cyclopentanone (IIId). The Rh(I) with (+)-DIPMC was found to proceed in a different manner from the Wilkinson-catalyzed cyclization.

引用

页码：4879 / 4888

页数：10

共 22 条

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