THE SENSITIZED FLUORESCENCE OF POLYETHYLENE PHTHALATE DOPED WITH 2-PYRAZINE CARBOXYLIC-ACID AND ITS COMPLEXES WITH EUROPIUM AND TERBIUM IONS

被引:10
作者
DEAZEVEDO, WM
DOSANJOS, PNM
MALTA, DL
DESA, GF
机构
[1] Lab. BS/TR2, Departamento de Quimica Fundamental, Universidade Federal de Pernambuco, 50739 Recife, PEI, Cidade Universitária
关键词
D O I
10.1016/0925-8388(92)90371-F
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work room temperature spectroscopic data are presented for synthesized polyethylene phthalate (as matrix) doped with 2-pyrazine carboxylic acid (Hpya) and its complex with Eu3+ or Tb3+ ions. These results reveal an interesting anomaly in the matrix fluorescence, which increases by a factor of 23, when doped with Hpya or its rare earth complexes. The fluorescence spectra of Eu3+ and Tb3+ ions are intense, which indicates that there is no significant interaction between the polymer matrix and the metal ions.
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页码:125 / 130
页数:6
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