THE 1ST MU-3-CARBONATO-BRIDGED TRINUCLEAR ZINC(II) COMPLEX CONTAINING METAL ATOMS IN 2 DIFFERENT COORDINATION ENVIRONMENTS

被引：24

作者：

CHEN, XM ^{[1
]}

DENG, QY ^{[1
]}

WANG, GYS ^{[1
]}

XU, YJ ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,STATE KEY LAB STRUCT CHEM,FUJIAN 350002,PEOPLES R CHINA

来源：

POLYHEDRON | 1994年 / 13卷 / 22期

关键词：

D O I：

10.1016/S0277-5387(00)83675-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Zn(NO3)2 with NaHCO3 and bpy in the presence of NaClO4 afforded a novel complex [Zn3(bpy)6(CO3)(H2O)2](ClO4)4(bpy).2H2O (1) (bpy = 2,2'-bipyridine), which has been structurally characterized by X-ray crystallography. The complex contains an unusual trinuclear cation with one pentacoordinate and two hexa-coordinate zinc atoms consolidated by a mu3-carbonato bridge.

引用

页码：3085 / 3089

页数：5

共 20 条

[1] AN L(3)ZNOH COMPLEX AS A FUNCTIONAL-MODEL OF THE ENZYME CARBONIC-ANHYDRASE [J].