BETA-(BEDT-TTF)(4)[(H2O)FE(C2O4)(3)]CENTER-DOT-PHCN - THE FIRST MOLECULAR SUPERCONDUCTOR CONTAINING PARAMAGNETIC METAL-IONS

被引：142

作者：

GRAHAM, AW ^{[1
]}

KURMOO, M ^{[1
]}

DAY, P ^{[1
]}

机构：

[1] UCL ROYAL INST GREAT BRITAIN, DAVY FARADAY RES LAB, LONDON W1X 4BS, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 20期

关键词：

D O I：

10.1039/c39950002061

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

beta''-(bedt-ttf)(4)[(H2O)Fe(C2O4)(3)].PhCN [bedt-ttf = bis(ethylenedithio)tetrathiafulvalene] is a superconductor [T(c)8.5(3) K]; from 9-300 K its magnetic susceptibility is dominated by the high-spin Fe-III and obeys the Curie-Weiss law (C = 4.375 emu K mol(-1), theta = -0.2 K).

引用

页码：2061 / 2062

页数：2

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