REARRANGEMENTS OF 3-METHYLCAR-4-EN-2-ONE

被引：22

作者：

BELLAMY, AJ

WHITHAM, GH

机构：

[1] Department of Chemistry, University of Birmingham, Edgbaston

来源：

TETRAHEDRON | 1968年 / 24卷 / 01期

关键词：

D O I：

10.1016/0040-4020(68)89025-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3-Methylcar-4-en-2-one has been shown to undergo ring opening to give 1-methyl-p-methane derivatives on treatment with reagents with attack cyclopropyl ketones, e.g. dissolving metals or mineral acids. The direction of ring opening appears to be controlled by stereo-electronic factors. © 1977.

引用

页码：247 / &

共 16 条

[1]

BAEYER A, 1896, BER DTSCH CHEM GES, V29, P6

[2]

BAEYER A, 1895, BER DTSCH CHEM GES, V28, P1600

[3] PHOTOCHEMICAL TRANSFORMATIONS .6. PHOTOCHEMICAL CLEAVAGE OF CYCLOHEXADIENONES [J].