CARBONYLATION OF ETHENE TO ACROLEIN IN THE PRESENCE OF THE EARLY LATE HETEROBIMETALLIC COMPLEX [ASPH4][(ETA-5-C5ME5)2ZR(MU-S)2RH(CO)2].THF

被引：31

作者：

KALCK, P ^{[1
]}

SERRA, C ^{[1
]}

MACHET, C ^{[1
]}

BROUSSIER, R ^{[1
]}

GAUTHERON, B ^{[1
]}

DELMAS, G ^{[1
]}

TROUVE, G ^{[1
]}

KUBICKI, M ^{[1
]}

机构：

[1] LAB SYNTH & ELECTROSYNTH ORGANOMET,CNRS,URA 33,F-21004 DIJON,FRANCE

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 04期

关键词：

D O I：

10.1021/om00028a014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [AsPh4][(eta5-CsMe5)2Zr(mu-S)2Rh(CO)27 complex has been prepared and fully characterized by an X-ray crystal structure analysis. In the presence of triphenylphosphine it initiates the carbonylation of ethene to give acrolein; upon addition of triethyl orthoformate the reaction is catalytic.

引用

页码：1021 / 1022

页数：2

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