P...N INTERACTION AND ITS EFFECT ON THE STRUCTURE AND PROPERTIES OF PHOSPHORYLATED ALPHA-AMINOKETONES DERIVATIVES

被引：11

作者：

BALITZKY, YV ^{[1
]}

PIPKO, SE ^{[1
]}

SINITSA, AD ^{[1
]}

CHERNEGA, AN ^{[1
]}

GOLOLOBOV, YG ^{[1
]}

机构：

[1] AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117334,RUSSIA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1993年 / 75卷 / 1-4期

关键词：

D O I：

10.1080/10426509308037391

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of alpha-aminoketones with P-chlorides in a basic medium are reported. Methods for the synthesis of DELTA4-1,3,2-oxazaphospholines and beta-amino-vinyl esters phosphorus acids are reported. Migration of phosphorus from N to O and enamin-imine isomerization are discussed for the phosphorylated aminoketones. Nucleophylic and electrophylic reactivity of cationes XV and XVI was studied.

引用

页码：167 / 170

页数：4