3,4-SECO-TRITERPENOID ACIDS AND OTHER CONSTITUENTS OF THE LEAF WAX OF HOYA-NAUMANII

被引:13
作者
BAAS, WJ
VANBERKEL, IEM
机构
[1] Department of Plant Ecology and Evolutionary Biology, University of Utrecht, 3512 PN Utrecht
关键词
HOYA-NAUMANII; ASCLEPIADACEAE; LEAF CUTICULAR WAX; TRITERPENES; DIHYDRONYCTANTHIC ACID; DIHYDROROBURIC ACID; DIHYDROCANARIC ACID; C4(23)-DIHYDRO-3,4-SECO-TRITERPENE-3-ACIDS;
D O I
10.1016/0031-9422(91)84221-D
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The main GC-detectable constituents of a methylated extract of Hoya naumanii leaf wax are n-hydrocarbons (ca 25%, mainly n-C31 and n-C33), the triterpenols beta-amyrin, lupeol and alpha-amyrin (ca 50% of the total wax), and the derived 3,4-seco-3-oic acid methyl esters: dihydronyctanthic acid, dihydrocanaric acid and dihydroroburic acid (ca 20%). In the non-methylated wax these ring-A-fissioned triterpenoids occur almost exclusively in the form of free acids.
引用
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页码:1625 / 1628
页数:4
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