REACTIONS OF POLYFLUOROARYL BROMIDES AND IODIDES WITH C-ELECTROPHILES, SI-ELECTROPHILES, GE-ELECTROPHILES, SN-ELECTROPHILES AND PB-ELECTROPHILES AND TRIS(DIALKYLAMINO)PHOSPHINES

被引：25

作者：

BARDIN, VV

PRESSMAN, LS

ROGOZA, LN

FURIN, GG

机构：

[1] Institute of Organic Chemisty

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 53卷 / 02期

关键词：

D O I：

10.1016/S0022-1139(00)82342-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of polyfluoroaryl bromides Ar(F)Br or iodides Ar(F)I with P(NR'2)3 and R3MX (R = alkyl; M = Si, Ge, Sn, and Pb; X = Cl, Br) led to the formation of Ar(F)MR3. The reactions of C6F5Br with P(NEt2)3 and C-electrophiles (CH3I, C6F5CF3 and (CF3)2C = CFC2F5) gave the products of pentafluorophenylation of these substrates.

引用

页码：213 / 231

页数：19

共 36 条

[1]

BARDIN VV, 1989, ZH ORG KHIM+, V25, P52

[2]

BARDIN VV, 1989, IAN SSSR KH, P2153

[3]

BARDIN VV, UNPUB J FLUORINE CHE

[4] SYNTHESIS AND PROPERTIES OF (TRIFLUOROMETHYL)TRICHLOROSILANE, A VERSATILE PRECURSOR FOR CF3SI COMPOUNDS [J].