CONVENIENT SYNTHESIS OF VINYLDIAZOMETHANES FROM ALPHA-DIAZO-BETA-KETO ESTERS AND RELATED SYSTEMS

被引：29

作者：

DAVIES, HML

HOUGLAND, PW

CANTRELL, WR

机构：

[1] Department of Chemistry, Wake Forest University, Winston-Salem, North Carolina 27109

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 07期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1080/00397919208019285

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of vinydiazomethanes were readily prepared by sodium borohydride reduction of alpha-diazo-beta-ketoesters followed by phosphorus oxychloride induced dehydration of the resulting alpha-diazo-beta-hydroxyesters.

引用

页码：971 / 978

页数：8

共 16 条

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[6] SYNTHESIS OF (+/-)-FERRUGININE AND (+/-)-ANHYDROECGONINE METHYL-ESTER BY A TANDEM CYCLOPROPANATION COPE REARRANGEMENT
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