UNEXPECTED PRODUCTS IN A KABACHNIK-FIELDS SYNTHESIS OF AMINOPHOSPHONATES

被引：9

作者：

GANCARZ, R

机构：

[1] Institute of Organic Chemistry, Biochemistry and Biotechnology, Technical University of Wrocław, 50-370 Wrocław

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1993年 / 83卷 / 1-4期

关键词：

1-AMINOPHOSPHONATES; 1-HYDROXYPHOSPHONATES; KABACHNIK-FIELDS REACTION; PHOSPHONATE-PHOSPHATE REARRANGEMENT;

D O I：

10.1080/10426509308034348

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In a Kabachnik-Fields synthesis of aminophosphonates derived from aromatic ketones the formation of hydroxyphosphonates, their rearrangement to corresponding phosphates and amine promoted decomposition of the last, leads to a number of unexpected products, which in some cases could be the only products of the reaction.

引用

页码：59 / 64

页数：6

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