ACTIVE SURFACE CARBON - A REACTIVE INTERMEDIATE IN THE PRODUCTION OF SYNTHESIS GAS FROM METHANE AND CARBON-DIOXIDE

被引：55

作者：

MARK, MF ^{[1
]}

MAIER, WF ^{[1
]}

机构：

[1] MAX PLANCK INST KOHLENFORSCH,D-45466 MULHEIM,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 15-16期

关键词：

D O I：

10.1002/anie.199416571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pulse chemisorption studies reveal that a subsequent reaction is part of the mechanism of the formation of synthesis gas from CH4 and CO2, known since 1928. In the first step CH4 is decomposed on a Rh/A12O3 catalyst into reactive surface carbon CS and H2; in the second step C8 reacts with CO2 to give CO, but it is still not clear whether this step is also catalyzed by Rh. Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：1657 / 1660

页数：4

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