CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM CHEMISTRY - SOME REACTIONS OF SUBSTITUTED VINYLIDENE COMPLEXES

被引：90

作者：

BRUCE, MI

SWINCER, AG

WALLIS, RC

机构：

[1] Department of Physical and Inorganic Chemistry, University of Adelaide, Adelaide

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 171卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)88073-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [Ru(C:CHPh)(PPh3)2(η-C5H5)]+ with MeOH, aqueous HBF4 or O2 afford {Ru[C(OMe)CH2Ph](PPh3)2(η-C5H5)}+, Ru(CH2Ph)(CO)(PPh3)(η-C5H5), and [Ru(CO)(PPh3)2(η-C5H5)]+ and PhCO2H, respectively; alkylation of Ru(C2R)(PPh3)2(η-C5H5) with R′3O+PF6 - gives complexes containing disubstituted vinylidene ligands, [Ru(C:CRR′)(PPh3)2(η-C5H5)]+. © 1979.

引用

页码：C5 / C8

页数：4

共 11 条

[1] ABUSALAH OM, 1974, J CHEM SOC DALTON, P2302
[2] DECARBONYLATION OF TRANSITION METAL ACYL COMPLEXES USING CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1)
ALEXANDER, JJ
WOJCICKI, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 15 (02) : P23 - +
[3] REACTIONS OF ALKYNYLPLATINUM(II) AND ALKENYLPLATINUM(II) COMPOUNDS .1. FORMATION OF ALKOXYCARBENE LIGANDS WITHIN COORDINATION SPHERE OF PLATINUM
BELL, RA
CHISHOLM, MH
COUCH, DA
RANKEL, LA
[J]. INORGANIC CHEMISTRY, 1977, 16 (03) : 677 - 686
[4] ALKYL GROUP ISOMERIZATION IN OXIDATIVE ADDITION OF ACYL CHLORIDES TO IRIDIUM(I) COMPLEXES
BENNETT, MA
CHARLES, R
MITCHELL, TRB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (09) : 2737 - 2743
[5] SOME NEW PI-CYCLOPENTADIENYLRUTHENIUM COMPLEXES
BLACKMOR.T
BRUCE, MI
STONE, FGA
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (14): : 2376 - &
[6] CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM CHEMISTRY - SYNTHESES AND DEPROTONATION OF SOME VINYLIDENE-RUTHENIUM COMPLEXES
BRUCE, MI
WALLIS, RC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 161 (01) : C1 - C4
[7] BRUCE MI, UNPUBLISHED
[8] CHISHOLM MH, 1973, ACCOUNTS CHEM RES, V6, P202, DOI 10.1021/ar50066a005
[9] DAVIS RD, 1978, COMMUNICATION
[10] STABLE DIMETHYL, METHYL, AND UNSUBSTITUTED VINYLIDENE COMPLEXES
DAVISON, A
SELEGUE, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (24) : 7763 - 7764

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