ISOMERIZATION OF ALLYL ALCOHOLS BY A WATER-SOLUBLE RUTHENIUM CATALYST IN A 2-LIQUID PHASE SYSTEM

被引：21

作者：

SASSON, Y

ZORAN, A

BLUM, J

机构：

[1] HEBREW UNIV JERUSALEM,CASALI INST APPL CHEM,JERUSALEM 91000,ISRAEL

[2] HEBREW UNIV JERUSALEM,DEPT ORGAN CHEM,JERUSALEM 91000,ISRAEL

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1979年 / 6卷 / 04期

关键词：

Compendex;

D O I：

10.1016/0304-5102(79)80034-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The principle of two-liquid phase catalysis has been demonstrated in the transformation of heptane soluble allyl alcohols and aqueous μ3-oxo-tri-ruthenium acetate to saturated ketones. The reaction with dec-1-en-3-ol was shown to take place at the liquids' interface while hex-1-en-3-ol and hept-1- en-ol undergo both interfacial and homogeneous isomerization. © 1979.

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页码：289 / 292

页数：4

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