INVESTIGATION ON VARIOUS BIS [(N-SUBSTITUTED-IMINO)(ALKOXY)METHYL]PLATINUM(II) DERIVATIVES AS LIGANDS TOWARDS GROUP-IIB HALIDES AND RHODIUM DICARBONYL CHLORIDE

被引：8

作者：

BANDITELLI, G ^{[1
]}

BANDINI, AL ^{[1
]}

MINGHETTI, G ^{[1
]}

BONATI, F ^{[1
]}

机构：

[1] UNIV CAMERINO,IST CHIM,I-62032 CAMERINO,ITALY

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1979年 / 9卷 / 06期

关键词：

D O I：

10.1080/00945717908069777

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The adducts A.ZaBr2, B.2nBr2, A.CdI2, A.CdBr2, C.CdI2, B.CdI2, C.HgCI2, C.2HgCl2, D.HgCI2, A.Rh(CO)2Cl were prepared from the corresponding halide and the ligand A, (Ph3P)(ArNC)Pt-[c(OMe)=NAr]2 B, (DFE)Pt{c(OMe)=NAr]2, C, (DPE)Pt-[c(OMe)=NMe]2or D, (DPE)Pt-|c(OMe)=NCgH112(Ar= p-tolyl, DPE= 1,2-bis(diphenylphosphino) ethane). These platinum(II) bidentate ligands are basic since they can be proton at ed at the two imino nitrogens, which are likely to be the donor sites in the adducts. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：539 / 555

页数：17

共 8 条

[1] GOLD(I) AND MERCURY(II) DERIVATIVES AS LIGANDS [J].