COBALT-CATALYZED PREPARATION OF DIIMINOFURAN DERIVATIVES THROUGH DOUBLE INSERTION OF ISOCYANIDE INTO A METAL-CARBON BOND

被引：16

作者：

SUGANO, K ^{[1
]}

TANASE, T ^{[1
]}

KOBAYASHI, K ^{[1
]}

YAMAMOTO, Y ^{[1
]}

机构：

[1] INST PHYS & CHEM RES, WAKO, SAITAMA 351, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 06期

关键词：

D O I：

10.1246/cl.1991.921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 2-bromoacetophenone with XylNC (Xyl = 2,6-xylyl) in the presence of Et3N and cobalt complex such as Co2(XylNC)8, CoBr2(XylNC)4, [Co(XylNC)5] (PF6) or Co(acac)3, gave 2,3-bis-N-(2',6'-xylyl)imino-5-phenyl-2,3-dihydrofuran. The structure was confirmed by an X-ray crystallographic analysis.

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页码：921 / 924

页数：4

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