CONVERSION OF TRIBASIC LEAD SULFATE TO LEAD DIOXIDE IN LEAD-ACID-BATTERY PLATES .1. RELATIONSHIP BETWEEN THE PHASE COMPOSITIONS OF PLATES IN THE CURED AND FORMED STATES

被引：7

作者：

ZERROUAL, L ^{[1
]}

CHELALI, N ^{[1
]}

TEDJAR, F ^{[1
]}

GUITTON, J ^{[1
]}

机构：

[1] LAB ION & ELECTROCHIM SOLIDE,F-38402 ST MARTIN DHERES,FRANCE

来源：

JOURNAL OF POWER SOURCES | 1994年 / 51卷 / 03期

关键词：

D O I：

10.1016/0378-7753(94)80110-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of the initial amount of H2SO4 added to lead powder on the phase compositions of plates in the cured and formed states has been studied. IR spectra, X-ray diffraction, scanning electron microscope observations, and wet-chemical analysis are used as techniques of investigation. It was found that the phase composition of the paste depends on the H2SO4:oxidized lead powder ratio. In addition, it is found that alpha- and beta-PbO2 are formed in the lead/acid battery positive plate from 3PbO.PbSO4.H2O. The amounts of these two compounds were strongly affected when varying the quantity of H2SO4 with respect to the lead powder.

引用

页码：425 / 431

页数：7

共 19 条

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