EFFECT OF HYDROGEN-BONDS ON THE THERMODYNAMIC BEHAVIOR OF LIQUID WATER

被引：414

作者：

POOLE, PH

SCIORTINO, F

GRANDE, T

STANLEY, HE

ANGELL, CA

机构：

[1] UNIV ROMA LA SAPIENZA,DIPARTIMENTO FIS,I-00185 ROME,ITALY

[2] NORWEGIAN INST TECHNOL,DEPT INORGAN CHEM,N-7034 TRONDHEIM,NORWAY

[3] BOSTON UNIV,CTR POLYMER STUDIES,BOSTON,MA 02215

[4] BOSTON UNIV,DEPT PHYS,BOSTON,MA 02215

来源：

PHYSICAL REVIEW LETTERS | 1994年 / 73卷 / 12期

关键词：

D O I：

10.1103/PhysRevLett.73.1632

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We propose an extension of the van der Waals equation which is designed to incorporate, in an approximate fashion, the effects of the network of hydrogen bonds that exist in liquid water. The resulting model qualitatively predicts the unique thermodynamic properties of water, including those of the deeply supercooled states. It also reconciles two proposals for the phase behavior of supercooled and stretched water and provides a thermodynamic origin for the observed polymorphism of the amorphous solid form of water.

引用

页码：1632 / 1635

页数：4

共 28 条

[1] WATER-II IS A STRONG LIQUID [J].