EFFECT OF HYDROGEN-BONDS ON THE THERMODYNAMIC BEHAVIOR OF LIQUID WATER

被引:414
作者
POOLE, PH
SCIORTINO, F
GRANDE, T
STANLEY, HE
ANGELL, CA
机构
[1] UNIV ROMA LA SAPIENZA,DIPARTIMENTO FIS,I-00185 ROME,ITALY
[2] NORWEGIAN INST TECHNOL,DEPT INORGAN CHEM,N-7034 TRONDHEIM,NORWAY
[3] BOSTON UNIV,CTR POLYMER STUDIES,BOSTON,MA 02215
[4] BOSTON UNIV,DEPT PHYS,BOSTON,MA 02215
关键词
D O I
10.1103/PhysRevLett.73.1632
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We propose an extension of the van der Waals equation which is designed to incorporate, in an approximate fashion, the effects of the network of hydrogen bonds that exist in liquid water. The resulting model qualitatively predicts the unique thermodynamic properties of water, including those of the deeply supercooled states. It also reconciles two proposals for the phase behavior of supercooled and stretched water and provides a thermodynamic origin for the observed polymorphism of the amorphous solid form of water.
引用
收藏
页码:1632 / 1635
页数:4
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