DIAGRAMMATICAL DERIVATION AND REPRESENTATION OF RAYLEIGH-SCHRODINGER PERTURBATION THEORY

被引:14
作者
SALZMAN, WR
机构
[1] Department of Chemistry, University of Arizona, Tucson
关键词
D O I
10.1063/1.1670546
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A method is presented for obtaining the various terms in the Rayleigh-Schrödinger perturbation theory to arbitrary order by means of diagrams. The prescription for obtaining the Nth-order correction to a particular zero-order eigenvector is to construct all diagrams of a certain type and associate an operator with each diagram. The method provides for the easy construction and display of Rayleigh-Schrödinger perturbation-theory corrections. The relationship of the present method to other work is discussed.
引用
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页码:3035 / &
相关论文
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