PRODUCTION OF ELECTRONICALLY EXCITED ATOMS - H+BR-2-]HBR+BR(STAR), H+HBR-]H-2+B(STAR)

被引：19

作者：

BLY, SHP

BRANDT, D

POLANYI, JC

机构：

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 65卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)80257-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By measurement of infrared chemiluminescence we have obtained for the branching ratio of the room temperature reaction H + Br2 (1), k*1/k1 = 0.015 ± 0.004 and for H + HBr (2), k*2/k2 ≤ 0.013. For H + Br2 → HBr(υ· ≤ 6) + Br (1), the detailed rate constant k(υ* = 6) = 0.014 ± 0.003 relative to k(υ· = 4) = 100. © 1979.

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页码：399 / 401

页数：3

相关论文

共 16 条

[1]

AIREY JR, 1966, S COMBUST, V11, P85

[2] ENERGY-DISTRIBUTION AMONG REACTION PRODUCTS .5. H+X2(X=CL, BR), D+CL2 [J].

ANLAUF, KG ;

POLANYI, JC ;

WOODALL, KB ;

MACDONAL.RG ;

HORNE, DS .

JOURNAL OF CHEMICAL PHYSICS, 1972, 57 (04) :1561-&

[3] ENTROPY AND CHEMICAL CHANGE .2. ANALYSIS OF PRODUCT ENERGY-DISTRIBUTIONS - TEMPERATURE AND ENTROPY DEFICIENCY [J].

BENSHAUL, A ;

BERNSTEIN, RB ;

LEVINE, RD .

JOURNAL OF CHEMICAL PHYSICS, 1972, 57 (12) :5427-+

[4] PRODUCT STATE DISTRIBUTION IN EXOERGIC CHEMICAL REACTIONS AND CONCEPT OF TEMPERATURE [J].

BENSHAUL, A ;

BERNSTEIN, RB ;

LEVINE, RD .

CHEMICAL PHYSICS LETTERS, 1972, 15 (02) :160-+

[5] STATISTICAL-MODELS AND PRIOR DISTRIBUTIONS IN THEORY OF CHEMICAL-REACTIONS [J].

BENSHAUL, A .

CHEMICAL PHYSICS, 1977, 22 (03) :341-366

[6]

BERNSTEIN RB, 1976, MODERN THEORETICAL C, V3, pCH7

[7]

BERNSTEIN RB, 1975, ADV ATOM MOL PHYS, V11, P216

[8] ENERGY-DISTRIBUTION AMONG REACTION-PRODUCTS .12. F+HBR-]HF(UPSILON' LESS-THAN-OR-EQUAL-TO-4)+BRSTAR(2P3/2,2P1/2) [J].

BRANDT, D ;

DICKSON, LW ;

KWAN, LNY ;

POLANYI, JC .

CHEMICAL PHYSICS, 1979, 39 (02) :189-199

[9] ENERGY-DISTRIBUTION AMONG REACTION-PRODUCTS .11. H + CLF-]HF + CL, HCL + F [J].

BRANDT, D ;

POLANYI, JC .

CHEMICAL PHYSICS, 1978, 35 (1-2) :23-34

[10]

CHARTERS PE, 1962, DISCUSS FARADAY SOC, V33, P107