METAL-ASSISTED REACTIONS .20. CATALYTIC TRANSFER HYDROGENOLYSIS OF PHENOLIC C-O BONDS

被引：31

作者：

BRIGAS, AF ^{[1
]}

JOHNSTONE, RAW ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 3BX,ENGLAND

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(00)97960-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

After conversion of phenols into O-pseudosaccharyl ethers (2) catalytic transfer hydrogenolysis with Pd/C catalyst and sodium phosphinate as hydrogen donor gave arenes (ArH) in good yield. As an example of the application of this reaction in synthesis, oestrone was converted into oestratrienone in a high yielding, one step reaction. © 1990.

引用

页码：5789 / 5790

页数：2

共 5 条

[1] STEROIDS CONTAINING RING A AROMATIC .2. HYDROGENOLYSIS OF RING A PHENOLS [J].