SELECTIVE RECOGNITION FOR HEAVY AND TRANSITION-METALS BY NOVEL POLYETHERS BEARING BIPYRIDINES, AND MOLECULAR CHIRALITY OF PSEUDOCROWN STRUCTURE IN THE CU(I) COMPLEX

被引：16

作者：

NABESHIMA, T ^{[1
]}

INABA, T ^{[1
]}

FURUKAWA, N ^{[1
]}

OHSHIMA, S ^{[1
]}

HOSOYA, T ^{[1
]}

YANO, Y ^{[1
]}

机构：

[1] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 45期

关键词：

D O I：

10.1016/S0040-4039(00)97112-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bisbipyridine derivatives linked by polyether chain 1 showed selective binding behavior to Zn(II) and Cu(I). The strength of the affinity is larger than that of 6, 6′-dimethylbipyridine derivative 2 because of the chelate effect of 1. Molecular chirality of the pseudocrown ether, 1-Cu(I)complex, was observed by 1H NMR spectroscopy at -28°C in the presence of Pirkle's reagent. © 1990.

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页码：6543 / 6546

页数：4

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