AN EXTENSION OF THE QUADRANT RULE IN OXIRANES TO NONALKYL SUBSTITUENTS - THE CD OF R(-)-EPICHLOROHYDRIN AND S(+)-EPICHLOROHYDRIN

被引：7

作者：

BASIL, A ^{[1
]}

BENTZUR, S ^{[1
]}

GEDANKEN, A ^{[1
]}

RODGER, A ^{[1
]}

机构：

[1] UNIV OXFORD,PHYS CHEM LAB,OXFORD OX1 3QZ,ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 180卷 / 05期

关键词：

D O I：

10.1016/0009-2614(91)85154-O

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The circular dichroism (CD) of epichlorohydrin (1-chloro-2,3-epoxypropane) in the gas phase reveals one structureless broad band peaked at 1710 angstrom. The CD sign of this band is according to the prediction made by the quadrant rule previously established for the oxirane chromophore. It seems that the quadrant rule can be applied to substituents other than alkyl groups.

引用

页码：482 / 484

页数：3

共 15 条

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