GRAFT-COPOLYMERIZATION OF ACRYLONITRILE AND ITS BINARY MIXTURE WITH 4-VINYL PYRIDINE ONTO ISOTACTIC POLYPROPYLENE POWDER BY PREIRRADIATION METHOD

被引:15
作者
KAUR, I
BARSOLA, R
MISRA, BN
机构
[1] Department of Chemistry, Himachal Pradesh University, Shimla, 171 005, Summer Hill
关键词
D O I
10.1002/app.1995.070561002
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Graft copolymerization of acrylonitrile (AN) and its binary mixture with 4-vinyl pyridine (4-VP) onto isotactic polypropylene powder in aqueous medium, using gamma-rays as an initiator, was studied. Optimum conditions for affording maximum percentage of grafting were evaluated. Rate of grafting (Rg) of AN and binary mixture (4-VP + AN) was determined as a function of total initial monomer concentrations. The graft copolymers were characterized by IR spectroscopy and thermogravimetric analysis. (C) 1995 John Wiley and Sons, Inc.
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页码:1197 / 1205
页数:9
相关论文
共 9 条
[1]  
Ang C.H., Garnett J.L., Levot R., Long M.A., Yen N.T., Photosensitized grafting of styrene 4-vinylpyridine and methyl methacrylate to polypropylene, Journal of Polymer Science: Polymer Letters Edition, 18, (1980)
[2]  
Nabieva A.M., Musaev U.N., Kurbanov Sh.A., Veasov A.V., Tsetlin B.L., Izve Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol., 27, (1984)
[3]  
Noh I., Yoon C.H., Hwang I.I.J., Nonmunjip‐Sanop Kwahak Kisul Yonguso, 7, (1980)
[4]  
Misra B.N., Sood D.S., Mehta I.K., J. Polym. Sci., Polym. Chem. Ed., 23, (1985)
[5]  
Mehta I.K., Sood D.S., Misra B.N., J. Polym. Sci., Polym. Chem. Ed., 27, (1989)
[6]  
Mehta I.K., Kumar S., Chauhan G.S., Misra B.N., J. Appl. Polym. Sci., 41, (1990)
[7]  
Kaur I., Barsola R., J. Appl. Polym. Sci., 41, (1990)
[8]  
Das S.K., Chatterjee S.R., Palit S.R., Studies in Chain Transfer. V. Acrylonitrile, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, (1955)
[9]  
Ham G.E., Chain transfer in acrylonitrile polymerization, Journal of Polymer Science, 21, (1956)