THERMODYNAMIC PROPERTIES OF N-PENTANE

被引:11
作者
GRIGORYEV, BA [1 ]
RASTORGUYEV, YL [1 ]
KURUMOV, DS [1 ]
GERASIMOV, AA [1 ]
KHARIN, VE [1 ]
PLOTNIKOV, SA [1 ]
机构
[1] GROZNY PETR & CHEM PROC RES INST,REVOLUT ST 21,GROZNY 364902,USSR
关键词
critical region; equation state; heat capacity; n-pentane; saturation properties; sound velocity; thermodynamic properties;
D O I
10.1007/BF00500841
中图分类号
O414.1 [热力学];
学科分类号
摘要
Specific volumes and isobaric heat capacity measurements are reported for n-pentane. The measurements were made in the liquid and vapor phases at temperatures ranging from the triple point (173 K) to the onset of dissociation temperature (700 K) and pressures up to 100 MPa including a wide region around the critical point. We are able to fit our data, as well as those of a number of other authors, to a single equation of state with 30 constants. This equation yields the density of n-pentane in the temperature range from 280 to 650 K at pressures up to 80 MPa and the caloric properties up to 500 K. Additional experimental investigations of the thermodynamic properties are required for temperatures above 500 K. Interpolating equations for the caloric properties on the saturated line and in the critical region are also presented. © 1990 Plenum Publishing Corporation.
引用
收藏
页码:487 / 502
页数:16
相关论文
共 49 条
[1]  
ALEKHIN AD, 1975, PHYSICS FLUID STATE, V3, P48
[2]  
Amirkhanov H.I., 1981, ISOCHORIC HEAT CAPAC
[3]  
ANISIMOV MA, 1974, USP FIZ NAUK+, V114, P249, DOI 10.3367/UFNr.0114.197410c.0249
[4]  
Artyukhovskaya L. M., 1970, Zhurnal Eksperimental'noi i Teoreticheskoi Fiziki, V59, P688
[5]  
BEATTIE JA, 1951, J AM CHEM SOC, V9, P4431
[6]  
BEATTIE JA, 1952, J AM CHEM SOC, V74, P4779
[7]  
BELINSKY BA, 1972, ACOUST J USSR ACAD S, V10, P335
[8]  
DAS TR, 1977, J CHEM ENG DATA, V22, P3, DOI 10.1021/je60072a014
[9]  
EDMISTER WC, 1984, APPLIED HYDROCARBON, V1
[10]  
Eucken A, 1941, Z PHYS CHEM B-CHEM E, V50, P143