ELECTRIC-FIELD EFFECTS ON PERSISTENT SPECTRAL HOLES - PERYLENE IN THE SHPOLSKII MATRIX NORMAL-HEPTANE

被引：11

作者：

ATTENBERGER, T

BOGNER, U

MAIER, M

机构：

[1] Naturwissenschaftliche Fakultät II-Physik, Universität Regensburg

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 180卷 / 03期

关键词：

D O I：

10.1016/0009-2614(91)87141-W

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Upon application of an electric field the spectral holes burned in different lines of the Shpol'skii multiplet of the centrosymmetric molecule perylene in the non-polar matrix n-heptane were splitted in two components, while the holes in the continuous background between the lines were broadened. The splitting and broadening were found to increase linearly with the electric field strength. The experimental results are discussed in terms of electric-field-induced variations of the gas-to-matrix shift of the electronic levels of perylene, which is caused by the dispersion interaction.

引用

页码：207 / 210

页数：4

共 18 条

[1]

ATTENBERGER T, IN PRESS

[2] STARK-EFFECT ON THE S1[-S0 TRANSITION OF THE 2 TAUTOMERIC FORMS OF CHLORIN STUDIED BY PHOTOCHEMICAL HOLE-BURNING IN NORMAL-HEXANE AND NORMAL-OCTANE SINGLE-CRYSTALS AT 1.2 K [J].