MAGNETIC CIRCULAR-DICHROISM FOR GENERATING CRYSTAL WAVE-FUNCTIONS

被引：4

作者：

FLUYT, L

VERHOEVEN, P

LAMBAERTS, H

BINNEMANS, K

GORLLERWALRAND, C

机构：

[1] University of Leuven, Department of Chemistry, B-3001 Heverlee

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1994年 / 207卷

关键词：

D O I：

10.1016/0925-8388(94)90174-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Ln(ODA)3(3-) complexes are characterized by a D3-point symmetry of the Ln3+ ion. It is illustrated how a specific angular modification of axial ligands towards a superposable D3h configuration is reflected by the magnetic circular dichroism spectra. In particular, the example of the induced electric dipole transition 5D2 <-- F-7(0) of Eu3+ is considered.

引用

页码：51 / 54

页数：4

共 7 条

[1] RARE-EARTH CARBOXYLATES .26. GEOMETRY OF MONONUCLEAR TRIS(OXYDIACETATO)CERATE(III) COMPLEX IN SOLID-STATE [J].