INCLUSIONAL COMPLEXATION BY CYCLODEXTRINS AT THE SURFACE OF SILVER AS EVIDENCED BY SURFACE-ENHANCED RESONANCE RAMAN-SPECTROSCOPY

被引：69

作者：

MAEDA, Y ^{[1
]}

KITANO, H ^{[1
]}

机构：

[1] TOYAMA UNIV,DEPT CHEM & BIOCHEM ENGN,TOYAMA,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 02期

关键词：

D O I：

10.1021/j100002a004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Preliminary results were described concerning the characterization of molecular assembly of azo dyes and chemisorbed monolayers of thiol-derivatized cyclodextrins on silver analyzed by surface-enhanced resonance Raman (SERR) spectroscopy. The results proved that methyl orange (MO) was included in the cavity of chemisorbed cyclodextrin (CD) derivatives on Ag. This is the first example to use SERR spectroscopy to detect inclusional complexation at the surface of a metal. Our findings suggest this approach may serve as a novel strategy to prepare an oriented thin layer of electroactive or photosensitive molecules.

引用

页码：487 / 488

页数：2

共 26 条

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