HEAT OF FORMATION OF POLY(CARBON MONOFLUORIDE)

被引：44

作者：

WOOD, JL

BADACHHA.RB

LAGOW, RJ

MARGRAVE, JL

机构：

[1] Department of Chemistry, Rice University, Houston

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 09期

关键词：

D O I：

10.1021/j100843a059

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Poly (carbon monofluoride) (CF)x has been burned in a fluorine bomb calorimeter. The heat of combustion of this material is -176.26 ± 0.15 kcal mol-1. Its heat of formation based on the currently accepted values for ΔHf° CF4 (g) is -46.7 ± 1.0 kcal mol-1. By combining this value with the observed heat of formation of CF(g), one can show that the carbon-fluorine bond energy in poly(carbon monofluoride)is ∼115 kcal mol-1, about the same as in other fluorocarbons.

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页码：3139 / &

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