DILUTE SOLUTION OF 2 NONELECTROLYTES IN A SOLVENT

被引：43

作者：

GARROD, JE

HERRINGT.TM

机构：

[1] Department of Chemistry, The University, Reading, Berkshire

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 06期

关键词：

D O I：

10.1021/j100726a040

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have obtained equations for the thermodynamic properties of dilute solutions of two nonelectrolytes in a solvent expressed as power series in the molalities, using the Stockmayer semigrand partition function. The coefficients of the power series depend on properties of the solvent containing small numbers of solute molecules. It is shown how these coefficients are related to the McMillan-Mayer coefficients for the osmotic pressure expressed as a power series in the number densities. Expressions for the coefficients are obtained for a mixture of hard spheres with a weak background potential.

引用

页码：1877 / &

共 21 条

[1] MIXTURES OF 1-1 ELECTROLYTES [J].