THE DISTRIBUTION AND QUANTITATION OF ORGANONITROGEN COMPOUNDS IN CRUDE OILS AND ROCK PYROLYSATES

被引：58

作者：

BAKEL, AJ

PHILIP, RP

机构：

[1] School of Geology and Geophysics, University of Oklahoma, Norman

来源：

ORGANIC GEOCHEMISTRY | 1990年 / 16卷 / 1-3期

基金：

美国国家科学基金会;

关键词：

ORGANONITROGEN COMPOUNDS; NITROGEN COMPOUNDS; OILS; PHOSPHORIA FORMATION; THERMIONIC SPECIFIC DETECTOR;

D O I：

10.1016/0146-6380(90)90054-4

中图分类号：

P3 [地球物理学]; P59 [地球化学];

学科分类号：

0708 ; 070902 ;

摘要：

Organonitrogen compounds are present in varying concentrations in aromatic fractions of various organic-rich geologic samples. Quinolines, benzoquinolines and carbazoles are the most important families of organonitrogen compounds in the aromatic fractions of crude oils and Phosphoria Formation pyrolysates. Aromatic fractions of oils generated from phosphatic shales contain higher concentrations of organonitrogen compounds than those from carbonate source rocks. Artificial maturation experiments on Phosphoria rocks at about 300-degrees-C yield high concentrations of quinolines relative to benzoquinolines and carbazoles, while higher temperature experiments yield high concentrations of benzoquinolines and carbazoles relative to quinolines. Organonitrogen compounds are potentially useful as indicators of the depositional environment of source rocks and maturity of crude oils.

引用

页码：353 / 367

页数：15

共 33 条

[1] DETERMINATION OF NITROGEN COMPOUND DISTRIBUTION IN PETROLEUM BY GAS-CHROMATOGRAPHY WITH A THERMIONIC DETECTOR [J].