CHEMISTRY IN SUPERACIDS .12. CARBONIC-ACID AND ITS MONOPROTONATION AND DIPROTONATION - NMR, ABINITIO, AND IGLO INVESTIGATION

被引：34

作者：

RASUL, G

REDDY, VP

ZDUNEK, LZ

PRAKASH, GKS

OLAH, GA

机构：

[1] UNIV SO CALIF,DONALD P & KATHERINE B LOKER HYDROCARBON RES INST,UNIV PK,LOS ANGELES,CA 90089

[2] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90089

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1993年 / 115卷 / 06期

关键词：

D O I：

10.1021/ja00059a020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structures and C-13 NMR chemical shifts of carbonic acid and its mono- and diprotonated forms were calculated using ab initio and IGLO methods, respectively. The results were compared with the experimentally obtained NMR data under superacidic conditions.

引用

页码：2236 / 2238

页数：3

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