SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURE OF CALCIUM OXO ETHOXIDE, [CA6(MU-4-O)2(MU-3-OET)4(OET)4].14ETOH

被引：50

作者：

TUROVA, NY ^{[1
]}

TUREVSKAYA, EP ^{[1
]}

KESSLER, VG ^{[1
]}

YANOVSKY, AI ^{[1
]}

STRUCHKOV, YT ^{[1
]}

机构：

[1] AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117813,RUSSIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 01期

关键词：

D O I：

10.1039/c39930000021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hexanuclear complex of calcium oxo ethoxide ethanol solvate, [Ca6O2(OEt)8].14EtOH 1 has been isolated after the prolonged refluxing of an ethanol solution of calcium ethoxide in the presence of the oxygen in air and studied by X-ray diffraction; the metal-oxygen framework is built of two [Ca4O4] cubes sharing a common [Ca2O2] face, which involves both oxo groups.

引用

页码：21 / 23

页数：3

共 25 条

[1]

Bellamy, 1957, INFRA RED SPECTRA CO

[2]

BOIX C, 1978, ACTA CRYSTALLOGR B, V34, P1463

[3]

Caulton K. G., 1990, ANGEW CHEM, V102, P1492

[4] PREPARATION, CRYSTAL AND MOLECULAR-STRUCTURE OF A HYDROCARBON SOLUBLE, VOLATILE OXO-ALKOXIDE OF BARIUM - H4BA6(MU-6-O)(OCH2CH2OCH3)14 [J].

CAULTON, KG ;

CHISHOLM, MH ;

DRAKE, SR ;

HUFFMAN, JC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (21) :1498-1499

[5] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE 1ST EXAMPLES OF MOLECULAR AGGREGATES OF BARIUM SUPPORTED BY ARYLOXIDE AND ALKOXIDE LIGANDS - [HBA5(O)(OPH)9(TETRAHYDROFURAN)8] AND [H3BA6(O)(OBUT)11(OCET2CH2O)(TETRAHYDROFURAN)3] [J].

CAULTON, KG ;

CHISHOLM, MH ;

DRAKE, SR ;

FOLTING, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (19) :1349-1351

[6] SYNTHESIS AND MOLECULAR-STRUCTURE OF A MONONUCLEAR BARIUM ARYLOXIDE ETHANOLAMINE COMPLEX, BA(2,6-BUT2C6H3O)2(HOCH2CH2NME2)4.2C7H8, EXHIBITING EXTENSIVE HYDROGEN-BONDING [J].

CAULTON, KG ;

CHISHOLM, MH ;

DRAKE, SR ;

FOLTING, K .

INORGANIC CHEMISTRY, 1991, 30 (07) :1500-1503

[7] A VERY LARGE CALCIUM DIALKOXIDE MOLECULAR AGGREGATE HAVING A CDI2 CORE GEOMETRY - CA9(OCH2CH2OME)18(HOCH2CH2OME)2 [J].

GOEL, SC ;

MATCHETT, MA ;

CHIANG, MY ;

BUHRO, WE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (05) :1844-1845

[8]

GRIGOREV AI, 1965, DOKL AKAD NAUK SSSR+, V162, P98

[9] THE SYNTHESIS AND STRUCTURE OF THE ALKALINE-EARTH METAL ORGANIC-COMPOUNDS [M(OAR)2(THF)N] [M = CA, N = 3 (1) OR 0 - M = BA, N = 4] AND [(CA(NR2)(MU-NR2)(THF))2], AND THE X-RAY STRUCTURE OF (1) (AR = C6H2BUT2-2,6-ME-4 - R = SIME3 - THF = OC4H8) [J].

HITCHCOCK, PB ;

LAPPERT, MF ;

LAWLESS, GA ;

ROYO, B .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (17) :1141-1142

[10]

KESSLER VG, 1991, ZH NEORG KHIM+, V36, P1662

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