CYANOANTHRACENE-SENSITIZED PHOTOOXIDATIONS OF N,N-DIBENZYLHYDROXYLAMINE AND ITS DERIVATIVES - OBSERVATION OF THE MARCUS INVERTED REGION IN BACK ELECTRON-TRANSFER WITHIN GEMINATE RADICAL-ION PAIRS

被引：4

作者：

SAKURAI, T

YOKONO, M

KOMIYA, K

MASUDA, Y

INOUE, H

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 22期

关键词：

D O I：

10.1039/c39930001689

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Back electron transfer within geminate radical ion pairs formed by electron transfer from the title hydroxylamines to singlet 9-cyano- and 9,10-dicyano-anthracenes in acetonitrile is shown to occur in the Marcus 'inverted region' and 'normal region', respectively.

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页码：1689 / 1690

页数：2

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