A MO(V) MONOPHOSPHATE WITH A TUNNEL STRUCTURE - K-3(MOO)(4)(PO4)(5)

被引：4

作者：

HOAREAU, T

LECLAIRE, A

BOREL, MM

GRANDIN, A

RAVEAU, B

机构：

[1] Laboratorie CRISMAT, CNRS URA 1318, ISMRA, 14050 Caen Cedex, Boulevard du Maréchal Juin

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1995年 / 114卷 / 01期

关键词：

D O I：

10.1006/jssc.1995.1009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Mo(V) monophospate has been synthesized for the first time. It crystallizes in the space group Pbca with a = 9.676(2) Angstrom, b = 14.366(2) Angstrom, and c = 28.391(5) Angstrom. The host lattice of this phosphate consists of corner-shaning MoO6 octahedra and PO4 tetrahedra forming two kinds of six-sided tunnels running along c where the K+ ions are located. Each PO4 tetrahedron shares its four apices with the Mo(V) octahedra, whereas each Mo(V) octahedron shares five apices with the tetrahedra, its sixth apex being free. Six-sided tunnels running along b that intersect the large tunnels running along a are also observed. The distribution of Kf in the different types of tunnels is studied. (C) 1995 Academic Press,Inc.

引用

页码：61 / 65

页数：5

共 8 条

[1]

Costentin G., 1993, REV INORG CHEM, V13, P77

[2] CRYSTAL-STRUCTURE OF THE MOLYBDENUM(V) DIPHOSPHATE KMOP2O8 ISOTYPIC WITH KNBP2O8 [J].