PHOTO-CHEMICAL OXIDATION OF ALCOHOLS BY FE3+, CU2+, AND AG+ IONS .2.

被引：11

作者：

RAJAN, S ^{[1
]}

RAMESH, D ^{[1
]}

机构：

[1] VIVEKANANDA COLL, DEPT CHEM, MADRAS 600004, INDIA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1978年 / 44卷 / 01期

关键词：

D O I：

10.1021/jo01315a031

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Very recently Stenberg3 reported the photochemical oxidation of aliphatic alcohols by FeCl3. Similar oxidation reactions are also known with ferric perchlorate. 4We report here, for the first time, that Ag+, and Cu2+ ions can photochemically oxidize alcohols and that these ions are better oxidizing agents than the reported Fe3+ ions. We have successfully oxidized aliphatic and aromatic alcohols, cyclic alcohols, and terpene alcohols with these metal ions in very high yields. K3Fe(CN)6 also oxidizes these alcohols. The reactions with Ag+ ions are very clean, fast, and convenient for workup. Table I gives the results. © 1979, American Chemical Society. All rights reserved.

引用

页码：138 / 140

页数：3

共 7 条

[1]

[Anonymous], IND J CHEM

[2] PHOTOCHEMICAL OXIDATION-REDUCTION AND PHOTOCATALYSIS - THE PHOTOCHEMICAL ACTIVITY OF FECL4-IN ALCOHOL AS OXIDIZING AGENT AND AS CATALYST [J].