ADDITION OF TIN(II) CHLORIDE TO PD2(PH2PCH2PPH2)2CL2 - CRYSTAL AND MOLECULAR-STRUCTURE OF PD2(PH2PCH2PPH2)2(SNCL3)CL

被引：69

作者：

OLMSTEAD, MM

BENNER, LS

HOPE, H

BALCH, AL

机构：

[1] Department of Chemistry, University of California, Davis

来源：

INORGANICA CHIMICA ACTA | 1979年 / 32卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0020-1693(00)91660-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Addition of tin(II) chloride to Pd2(dpm)2Cl2 (dpm is Ph2PCH2PPh2) produces Pd2(dpm)2(SnCl3)Cl. The crystal structure of the latter complex reveals that the tin(II) chloride has inserted into the PdCI bond and that a nearly linear PdPdSn unit it present infrared and electronic spectral evidence indicates that carbon monoxide and sulfur dioxide insert into the Pd-Pd bond of Pd2(dpm)2(SnCl3)Cl. Spectroscopic evidence for the formation of Pd2(dpm)2(SnCl3)2 is described. © 1979.

引用

页码：193 / 198

页数：6

共 12 条

[1]

BAIRD MC, 1967, J INORG NUCL CHEM, V29, P67

[2]

Batley G. E., 1968, INORG NUCL CHEM LETT, V4, P577

[3] REVERSIBLE INSERTION OF SULFUR-DIOXIDE INTO PALLADIUM-PALLADIUM BONDS - PREPARATION AND STRUCTURE OF PD2(MU-SO2)(PH2PCH2PPH2)2CL2 [J].