ENERGY OF THE TCNQ TRIPLET-STATE IN PHENAZINE-TCNQ AND FLUORENE-TCNQ CRYSTALS

被引：8

作者：

FRANKEVICH, EL ^{[1
]}

CHABAN, AN ^{[1
]}

TRIEBEL, MM ^{[1
]}

VONSCHUTZ, JU ^{[1
]}

WOLF, HC ^{[1
]}

机构：

[1] UNIV STUTTGART,INST PHYS 3,W-7000 STUTTGART 80,GERMANY

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 177卷 / 03期

关键词：

D O I：

10.1016/0009-2614(91)85031-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using magnetic field effect measurements of the fluorescence of oriented phenazine-TCNQ (Ph/TCNQ) and fluorene-TCNQ (F/TCNQ) crystals as a function of excitation power and temperature, we were able to reveal the single depletion path S--> (T + T) which is thermally activated: for F/TCNQ with DELTA-E = 3226 cm-1, for Ph/TCNQ DELTA-E = 1130 cm-1. Assuming 2E(T) = E(s) + DELTA-E, the triplet energies are 8865 cm-1 for Ph/TCNQ and 9865 cm-1 for F/TCNQ. The difference in the energy can be attributed to different stabilization energies of the ground states of the complexes.

引用

页码：283 / 286

页数：4

共 12 条

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