LI10P4N10 - A LITHIUM PHOSPHORUS(V) NITRIDE CONTAINING THE NEW COMPLEX ANION P4N10(10-)

被引：46

作者：

SCHNICK, W

BERGER, U

机构：

[1] Institut Für Anorganische Chemie, Universität Bonn, W-5300

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 07期

关键词：

D O I：

10.1002/anie.199108301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The nitrogen analogue of molecular P4O10 is contained in Li10P4N10 as the new P4N 1010− ion 1. The packing of the complex units in the solid is significantly more compact than in phosphorus(v) oxide. This can be attributed to the ionic structure, which, surprisingly, is derived from the cubic As4O6 structure. The title compound is synthesized by solid‐state reactions of binary nitrides. (Figure Presented.) Copyright © 1991 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：830 / 831

页数：2

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