HETEROLYTIC C-O CLEAVAGE IN ARYLETHERS ACTIVATED BY [FE(ETA(5)-C5H5)](+)

被引：29

作者：

MOULINES, F

DJAKOVITCH, L

DELVILLEDESBOIS, MH

ROBERT, F

GOUZERH, P

ASTRUC, D

机构：

[1] UNIV BORDEAUX 1, CHIM ORGAN & ORGANOMET LAB, CNRS, URA 35, F-33405 TALENCE, FRANCE

[2] UNIV PARIS 06, CHIM MET TRANSIT LAB, CNRS, URA 419, F-75252 PARIS 05, FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 04期

关键词：

D O I：

10.1039/c39950000463

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The C-O bond of Fe(eta(5)-C5H5)(+) complexes of aryl ethers is cleaved smoothly by reaction of Bu(t)OK in THF or KOH in DME, yielding pi-phenate complexes; transetherification can also be achieved in situ at room temperature.

引用

页码：463 / 464

页数：2

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