HETEROMETALLIC CARBONYL CLUSTER OXIDE - FORMATION, STRUCTURE AND REACTIVITY OF WRE2 OXO-ACETYLIDE CLUSTER COMPOUNDS

被引：23

作者：

CHI, Y ^{[1
]}

CHENG, PS ^{[1
]}

WU, HL ^{[1
]}

KWANG, DK ^{[1
]}

SU, PC ^{[1
]}

PENG, SM ^{[1
]}

LEE, GH ^{[1
]}

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 16期

关键词：

D O I：

10.1039/c39940001839

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cluster [WRe2(C(5)Me(5))(O)(CO)(8)(CCPh)] 1a possessing a terminal oxo ligand is prepared by treatment of the acetylide cluster [WRe2(C(5)Me(5))(CO)(9)(CCPh)] with O-2 or N2O; hydrogenation of 1a affords three isolable clusters, showing an example of oxo-ligand mediated sequential conversion of acetylide to alkenyl and alkylidene.

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页码：1839 / 1840

页数：2

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